École Nationale Supérieure de Chimie de Lille, France
List of available PhD theses
Preparation of olefin block copolymers
The thesis will be focused on the preparation of block copolymers based on olefin and diene monomers by coordination copolymerizations. The focus will be on copolymers with blocks of different properties, e.g. hard and soft blocks. Principles of coordination chain transfer polymerization and chain-shuttling polymerization will be applied. Introduction of polar functional groups will also be of interest. The work will include organometallic synthesis of catalysts, polymerization experiments in presence of various transfer agents and full characterization of obtained polymers.